72. One-step aerosol synthesis of KBaTeBiO₆ for CO₂ photoreduction

One-step aerosol synthesis of a double perovskite oxide (KBaTeBiO₆) as a potential catalyst for CO₂ photoreduction

Hao Zhou,Mojgan Kouhnavard,Sungyoon Jung,Rohan Mishra and Pratim Biswas, Nanoscale (2021)

This study presents a comprehensive investigation on the aerosol synthesis of a semiconducting double perovskite oxide with a nominal composition of KBaTeBiO₆, which is considered as a potential candidate for CO₂ photoreduction. We demonstrate the rapid synthesis of the multispecies compound KBaTeBiO₆ with extremely high purity and controllable size through a single-step furnace aerosol reactor (FuAR) process. The formation mechanism of the perovskite through the aerosol route is investigated using thermogravimetric analysis to identify the optimal reference temperature, residence time and other operational parameters in the FuAR synthesis process to obtain highly pure KBaTeBiO₆ nanoparticles. It is observed that particle formation in the FuAR is based on a combination of gas-to-particle and liquid-to-particle mechanisms. The phase purity of the perovskite nanoparticles depends on the ratio of the residence time and the reaction time. The particle size is strongly affected by the precursor concentration, residence time and furnace temperature. Finally, the photocatalytic performance of the synthesized KBaTeBiO₆ nanoparticles is investigated for CO₂ photoreduction under UV-light. The best performing sample exhibits an average CO production rate of 180 μmol g⁻¹ h⁻¹ in the first half hour with a quantum efficiency of 1.19%, demonstrating KBaTeBiO₆ as a promising photocatalyst for CO₂ photoreduction.